Symmetry in the design of NMR multiple-pulse sequences.
نویسنده
چکیده
The symmetry principles of NMR pulse-sequence design are summarized. The discussion is guided by an analogy with tiling schemes in the decorative arts. The symmetry operations for NMR pulse sequences are discussed in terms of excitation field modifiers and temporal modifiers. The quantum operators which describe the effect of these modifiers on the excitation field spin Hamiltonian are provided. The symmetry transformations of spin propagators, and the different types of pulse-sequence elements are discussed. The common types of symmetry expansion are treated using the propagator transformations and the Euler angles for the excitation field propagators. The selection rules associated with symmetrical pulse sequences are discussed using average Hamiltonian theory.
منابع مشابه
Symmetry principles for the design of radiofrequency pulse sequences in the nuclear magnetic resonance of rotating solids
Some new symmetry theorems are presented which simplify the task of designing multiple-pulse radio-frequency pulse sequences in magic-angle-spinning solid-state NMR. The symmetry theorems apply to sequences denoted R N, which n consists of N repetitions of a pulse sequence element R, alternating in phase between the values "pnrN. Each R element ideally rotates the spins by an angle p about the ...
متن کاملThe Optimization of Magnetic Resonance Imaging Pulse Sequences in Order to Better Detection of Multiple Sclerosis Plaques
Background and objective: Magnetic resonance imaging (MRI) is the most sensitive technique to detect multiple sclerosis (MS) plaques in central nervous system. In some cases, the patients who were suspected to MS, Whereas MRI images are normal, but whether patients don’t have MS plaques or MRI images are not enough optimized enough in order to show MS plaques? The aim of the current study is ...
متن کاملA fast, stable quadrature phase generator for multiple-pulse NMR
Modern NMR pulse sequences usually consist of a series of radiofrequcncy (rf) pulscs having orthogonal (quadrature) phases. While there are a variety of situations where pulse accuracy is important, 1 it is especially critical for solid-state multiple-pulse NMR.2 In fact, multiple pulse sequences developed for phase measurement excced the accuracy of traditional electronic phase measuremen t te...
متن کاملOptimal control of coupled spin dynamics: design of NMR pulse sequences by gradient ascent algorithms.
In this paper, we introduce optimal control algorithm for the design of pulse sequences in NMR spectroscopy. This methodology is used for designing pulse sequences that maximize the coherence transfer between coupled spins in a given specified time, minimize the relaxation effects in a given coherence transfer step or minimize the time required to produce a given unitary propagator, as desired....
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 128 5 شماره
صفحات -
تاریخ انتشار 2008